A Multi-Functional Tool - Cyclopentadienyl Re and 99mTc Complex Synthesis on Highly Functionalised Arenes
نویسندگان
چکیده
The biologically relevant arenes ethyl salicylate and salicylic amide as well the fluorescent coumarin pyrene units were functionalized with a cyclopentadiene unit. Re 99mTc complexes of latter two synthesized fully characterized. During crystallization ligands, [2+2] [6+6] cycloadditions observed for modified coumarin. A light-induced mechanism, supported by DFT calculations, is proposed these reactions. properties based cyclopentadienes their corresponding investigated .
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ژورنال
عنوان ژورنال: Journal of Organometallic Chemistry
سال: 2022
ISSN: ['1872-8561', '0022-328X']
DOI: https://doi.org/10.1016/j.jorganchem.2022.122281